第28回CIMoSセミナー
Chirality related properties of helicene and tetrathiafulvalene materials
Chirality manifests itself in many areas of physics, chemistry and biology, where objects or materials can exist in two non super-imposable forms, one being the mirror image of the other.[1] Introduction of chirality into conducting systems is a topic of much current interest as it allows the preparation of multifunctional materials in which the chirality might modulate the structural disorder or expresses its influence through the electrical magneto-chiral anisotropy effect.[2] The access to various chiral electroactive precursors for molecular conductors is therefore of paramount importance.[3] Our endeavour towards chiral molecular superconductors will be outlined.[4]
Another chirality related effect is the chirality induced spin selectivity (CISS) consisting in a preferential spin transmission through a chiral material. We will discuss helicene and tetrathiafulvalene based materials showing this property.[5]
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[1] G. H. Wagnière, On Chirality and the Universal Asymmetry 2007, Wiley-VCH, Weinheim.
[2] F. Pop, P. Auban-Senzier, E., Canadell, G. L. J. A. Rikken, N. Avarvari, Nat. Commun. 2014, 5, 3757.
[3] a) N. Avarvari, J. D. Wallis, J. Mater. Chem. 2009, 19, 4061; b) F. Pop, N. Zigon, N. Avarvari, Chem. Rev. 2019, 119, 8435.
[4] N. Mroweh, C. Mézière, F. Pop, P. Auban-Senzier, P. Alemany, E. Canadell, N. Avarvari, Adv. Mater. 2020, 32, 2002811.
[5] Y. Liang, K. Banjac, K. Martin, N. Zigon, S. Lee, N. Vanthuyne, F. A. Garcés-Pineda, J. R. Galán-Mascarós, X. Hu, N. Avarvari, M. Lingenfelder, Nat. Commun. 2022, 13, 3356.
日時 | 2023年3月10日(水) 16:00〜17:00 |
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場所 | 分子科学研究棟 研究棟201号室 |
題目 | Chirality related properties of helicene and tetrathiafulvalene materials |
講演者 | Prof. Narcis Avarvari (Laboratoire MOLTECH-Anjou, CNRS - Universite d'Angers, France) |